diodes can be like signal diodes 1N4148. Not backwards in order to pull MCLR low to reset and that is considering you do LOW VOLTAGE PROGRAMMING setting, if not doing that then would use the 2n3906 or any NPN to pull down all the slaves through the diodes. The @ RESET is an assembly instruction using the @ for PBP to do machine code directly ( I think you know all that stuff)...... so if you want a hard reset after ICSP then yes to use MCLR but if chips are running, you could give instruction to GOTO reset.
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