I don't have your hardware so I cannot set this up here and test it. I don't have the time for that anyway. I can only tell you I've used the code many, many times with 12F629, 12F675 and 12F673 and ASK RF modules.
You will only see garbage when you connect the transmitter TXD pin to RS232 as it is sending NEC protocol not RS232 protocol.
However, if you go back to your original approach, using SerOut & SerIn, you can send RS232 from the transmitter which might serve as a sanity check.
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