Depends on the viewing angle.
If you've got a 35kmcd LED with a viewing angle of 170 degrees, then, yes, that's a seriously bright LED. If that same 35kmcd LED only has a viewing angle (1/2 theta) of 10 degrees, then it won't be so bright.
LEDs don't run on voltage...get that idea out of your head. Yes, they need voltage...'nuff said.Can i just double check that a 4V LED will be fine running on 12V if i use PWM? The average would end up being 3V. Im sure it was someone from here who said that would work but i dont remember who.
It's CURRENT that makes an LED work. Yes, you have to have enough voltage to get the current required, which is why you also sometimes need a current limiting resistor. You start pumping 12v thru a single LED (unless it's rated for 12v of course), and you WILL burn it up sooner rather than later. If you've got 12v PWM running at 25% duty cycle, yes, the average would be about 3v-ish, but you're still hitting the LED with 12v. Again, if it's rated for that 12v, then I suppose you'll be fine. Otherwise, look to have a bunch of open LEDs eventually.
Do yourself a favor and get a copy of 'The Art of Electronics' and do a bit of reading. It's my 'bible', great book, will teach you a lot about a lot of stuff.
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