You should be able to drive a PIC directly from one LiPo, no regulators need.
There's a few PICs out there that have a built-in .6v reference which you could 'reference against'.I'm not going to use voltage reference to keep it simple and ADC probably should work within 1%-3% accurate.
If you think it'll run, go with it... I don't think it'll run and last, but that's just me.As you can see 1 PDIP microchip, 1 LDO, 1-2 capacitors and just connector glued and soldered directly to microchip.
Same thing with the USB, the connector, 2 wires to the PIC (D+/D-), an extra cap, and the right firmware.Using software rs232 I don’t need Max232 so I can just use serial female connector with 2 resistors and connect it directly to microchip whenever I need to upload the data.





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