Hi PICante,
What are you using as Vref for the ADC? If you're using your PIC supply as Vref and it is exactly 5.00V you still only get ~2counts per degree C. 5.0V divided by 1024 (10bits) makes one LSB 4,89mV.
If you aren't using an external Vref for the ADC, I'd try that and see what happens. A Vref of 1.024V in this case would let you meassure up to 102.4°C with a resolution of 0.1° - in a perfect world.
HTH
/Henrik.
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