Ok,
I've tried replacing the 20k resistor with 1M (largest I have to hand), and the results are much the same - a clear voltage swing when just connected to my voltmeter, but almost none when also connected to the pic.
Have I understood your suggestion correctly? I've attached a (crude) diagram of my setup.
Incidentally, I tried shielding the sensor from ambient light, but there was a negligible difference in readings.
Thanks again!
Bookmarks