The PIC (and everything else mentioned so far) will run just fine off 4.5v, and the occassional switchover to 6v probably won't hurt it much either. Datasheets say 7V is 'absolute maximum' rating, not recommended for any length of time. I've accidentally ran a couple of my PIC's at 9v before, they still run, not saying they're not damaged and won't fail before the others, but they do still work.
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