Hi,
For the supply, if the two PICS have a COMMON GROUND and BOTH a very close to 5 v supply ( do not forget PIC protection diodes on the inputs ...), I don't see any problem ... as your sensor impedance is low enough.
For common Ground ... keep in mind there should be only 1 common ground connection point to avoid "ground loops" ...
Alain
a scheme of each of your ADCs inputs could help greatly too ...
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Why insist on using 32 Bits when you're not even able to deal with the first 8 ones ??? ehhhhhh ...
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IF there is the word "Problem" in your question ...
certainly the answer is " RTFM " or " RTFDataSheet " !!!
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