RUBiksCUbe:
Thats a good diagram. I wish I had that when I was still coding. Do you have one of those for the vertical synch? I cant find the timing for it anywhere.
Here's a link to where I got the Hsync diagram (they also have one for Vsync) http://www.sxlist.com/techref/io/video/ntsc.htm

You'll notice if you look at the FLD 4 example, that they show 6 equalizing pulses ocurring before and after the Vsync. Most modern TV's don't need these any more. This was originally used to help the older sets lock in properly, which is also why these sets had horizontal and vertical adjustments, something you also don't see any more. As for the Vsync pulse, instead of it being one long pulse, it is actually made up of both long and short pulses. Essentially it is just hsync turned upside down for 3 scan lines. Therefore the total length of the Vsync pulse is approximately 191 usec, and occurs approximately every 16 msec.

A good way to produce these signals is to use the PIC's internal counters in an interrupt routine. Or if you have an HPWM on board, you can also mimic these sync pulses by properly setting the duty cycle and base frequency (this is easily done via PBP).

Have fun,