I'd try increasing the baudrate even further.
According to Wikipedia 256kbits/second is a predefined serial port speed in Windows so you "should" have that available without doing anything "special". If you put a RS485 tranceiver at each end you get up into the Mbits/seconds without much problem but then something like DMA on the PIC-side would start to make sense.


Running all at 2.0V. It's actually the 18LF26J53 (not sure if I mentioned that above). The FT231X is good down to 1.8 V I believe.

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