I ran into this exact issue with this exact PIC! I swapped over to a PIC16F18323. I wanted to monitor battery voltage. If input voltage were to start dropping with ADC referencing Vdd, I may never see a dying battery until it was too late. Referencing ADC to 2.048 volts with a voltage divider on the input made it more precise. I think that's similar to what you are trying to do.
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