Not normally if you've configured it as Analogue Input. If you need to use it as digital, you must recondfigure as such... there's no problem doing this mid-program flow.
For a concise answer, most PIC pins have a simplified block diagram of it's configuration in the Datasheet. If it looks like the pin is simultaneously connected to both analog and digital circuitry regardless, then there's no harm doing an experiment to see if it works in Digital whilst configured for Analogue.
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