For a test-setup I did I used some cheap 4-wire single strand telephone wire. 4 slaves with 30 metres of cable between each (90m total) it worked fine but it was "only" 90m and in a relatively "quite" office environment. For a real-life setup I'd use twisted pair cable, any old twisted pair cable will most likely work just fine but, like tumbleweed says, CAT5 or whatever is probably hard to beat in price and accessabillity.
I believe CAT5 cable is has a specified impedence of ~100ohm while for RS485 it ideally should be 120ohm. If you're not running super high bit rates, close to the maximum speed of the tranceivers I don't think it'll matter much.
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