Hi, Tony
My thoughts ...
if you want to place your supply in a car ( and have fear of what COULD happen ) ... you should use regulators dedicated to automobile use, that are specially designed to whithstand the spikes and other funnies you can find on car 12v lines ...
ST ( between others ) has developped a whole line of such rugged regulators.
So just browse their catalogs, automotive applications sector ... and see what you can get from your dealer. ( Farnell, Mouser, Digikey ...)
or simply READ what manufacturers show into their Datasheets ... 
Alain
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Why insist on using 32 Bits when you're not even able to deal with the first 8 ones ??? ehhhhhh ...
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IF there is the word "Problem" in your question ...
certainly the answer is " RTFM " or " RTFDataSheet " !!!
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