Looking at the specs, you have a minimum of 16 KHz and a maximum of 96 KHz for the sampling frequency (see the attached picture). The corresponding minimum clocking signal for Fs=16 KHz is 4.096 MHz (256*Fs). The table that gives you the 8.192 MHz is just a list of the typical values.
I am not sure either that the internal osc can go fast enough for this PCM chip. Now, if you use an external 20 MHz crystal, which is typical for this 18F4550 PIC, I don't see why it wouldn't work unless I'm missing something here. In this case, I would say that Fosc=20 MHz and the output at RA6 would be Fosc/4 = 5 MHz, which is within the allowed boundaries.
Let us know if you made it work or not.
Robert
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