As far as I know, any of the PIC® that work in the PicKit1 do not have hardware serial (UART), so it does not matter. The only exception I can think of is the ADC pins, you may want to save these for sensors, but they will still work for serial.
Pin 5
Common, ground, zero rail...
This must be connected to both devices for any serial to work.
Pin 2
Data is sent to the PC via this pin. PIC® -->> PC
Pin 3
Data is sent to the PIC® via this pin. PIC® <<-- PC
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