I can't answer questions on your programmer as I don't have one.
Your CONFIG settings should match those preset into the program, but whether your programmer is actually programming them is another qustion.
If MCLR needs a pull-up, then the CONFIGS sure don't match (or yor PIC is broke)... it could be there's another tick-box in your software for your programmer that needs activating. My software for example has the ability to program the PIC and leave the CONFIGS untouched unless I've set it on another screen. This also means that GPIO4 could have OSC coming out of it instead of it being used for I/O.
Worst case scenario is I can send you my PIC, but it means you can't make changes if your programmer is misbehaving.
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