Hi Maxster,
Measure the voltage between the Black and white wires in the normal state, then measure the voltage across those same wires in an alarm state. If there is more than 2 volts IN ALARM then you could connect the LED side of an optoisolator to these points then disable the buzzer. Then connect the phototransistor side of the optoisolator to your external circuitry to do whatever it is you need to activate.
PLEASE REMEMBER THIS SHOULD NOT BE USED IN ANYWAY SHAPE OR FORM AS A LIFESAFETY DEVICE. THIS IS ONLY FOR EDUCATIONAL PURPOSES.
Now if you can get your hands on a "systems oriented" type of 4 wire smoke detector then you can supply 12 or 24 volts DC to the detector and you have a built-in set of Normally Open relay contacts that you can use to trigger whatever it is you are trying to activate.
I have not included and diagrams only because I do not know your level of knowledge. Let me know.
Hope this helps you out.
BobK
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