Ok, Mel
You're talking resolution while I'm talking accuracy ...
DS already give .0625°C resolution ... but that do not mean anything because you only know you are inside the +/- 0.5 °C error gap.
LM 335 have your ADC resolution ... but always an "out of the box" +/- 0.5 °C precision
That is why I say ( and repeat ... ) you can't get a better reading WITHOUT a calibration ... or comparison with a known reference.
Even the MS5534 ( 16 bits! ) which comes with its calibration coeffs ... is given for a GUARANTEED +/- .8°C accuracy ...
For NTC's the problem is the +/- 5 to 20% value tolerance ... that need an individual curve adjustment to each sensor ( only 1 point ... yes... but one point calibration ! )
The only **predictable** High accuracy sensors are Platinium RTD's ... But , ... How much to pay for a class A probe ??? ...
Temp and Thermal measurements are always funny ... and make you humble !!!
Alain
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Why insist on using 32 Bits when you're not even able to deal with the first 8 ones ??? ehhhhhh ...
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IF there is the word "Problem" in your question ...
certainly the answer is " RTFM " or " RTFDataSheet " !!!
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